Preheat the oven to 350℉/177℃. Grease and parchment line three 6-inch round cake pans and set aside.
In a large bowl, whisk together the flour, sugar, cocoa powder, baking soda, baking powder and salt.
2 cups all-purpose flour, 2 cups granulated sugar, ¾ cup black cocoa powder, 1½ teaspoons baking soda, 1 teaspoon baking powder, 1 teaspoon kosher salt
In a separate bowl, whisk together the eggs and egg yolks, oil, butter, sour cream and milk until smooth, then add to the dry ingredients and mix until incorporated.
2 large eggs, 2 large egg yolks, ½ cup vegetable oil, ½ cup unsalted butter, ¾ cup full-fat sour cream, ¼ cup whole milk
Add in the hot coffee and mix until fully combined, careful not to over mix (or slosh it over the sides).
1 cup very hot coffee or water
Divide the batter evenly between the three 6” pans and bake on the middle rack for 30-40 minutes or until a toothpick inserted in the center comes out clean.
Allow the cakes to cool in the pan for 15 minutes, then remove, wrap entirely in plastic wrap, and freeze for 1-2 hours. Store the cake layers top side down, bottom side up.